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Need for Stain Protection - Sketch - Unique Characteristics - Stain Mechanism - Stain Prevention - Products Comparison - Road Facilities - Product Features

ASGARDPRO™

Specialized anti-static coating

For tunnels, subways, guardrails and other ROADway facilities

Delphi Labs is preparing to introduce to the US market a proven and innovative protective coating that will turn the tile surfaces of tunnels into easy-maintenance surfaces. The ultra-thin silica coating includes zinc oxide to reduce static electricity and iodine to resist mold. This product is already being purchased by the Japan Highway Association for similar applications. We expect this product to be available for use in the United States by the summer of 2006.

This product is formulated and manufactured by Sketch Co., Ltd, a pioneer in binder technology.

The Development of the Product

Today, in the stain prevention market, photocatalytic self-cleaning coatings using titanium dioxide are rapidly expanding the market throughout the world. However, because photocatalysts have the ability to break down organic matter, primers are absolutely required when applying to surfaces that are common in highway-related signage, safety equipment and building materials such as paint, polycarbonates, acrylics, FRP (fiberglass reinforced plastics) and resins. Unfortunately, there are no inorganic primers available today that adhere strongly to these resins. Moreover, because polycarbonates and acrylics have complex molecular structures, when the surface becomes water-repellant, the surface attracts dirt and grime (because of static electricity) and becomes easily tarnished or stained. There is thus a strong need for an inorganic primer or a top coat with dual capabilities of photocatalysis and reducing static electricity and still bind strongly to these resin surfaces

Furthermore, there is a need for a stain prevention coating that can substitute for photocatalytic coatings in locations that do not receive much light such as tunnels, subways, underground shopping areas and the north faces of buildings and that can be easily cleaned by periodic rinsing with water. And, especially in humid areas which give rise to mold problems, there is a need for a coating with an anti-mold function.

After many years of research, based upon our company’s binder technology, we have successfully developed a binder and a primer for resins that resolves the issues identified above. To our inorganic binder, we have added ATO (antimony doped tin oxide from Mitsubishi Materials) which has superb anti-static electric functions. To this strong base, we have added a powerful visible-light photocatalyst composed of titanium dioxide for those areas receiving light and an anti-mold formulation with iodine and silver ions for those areas not receiving adequate light.

We have also succeeded in preparing a firm inorganic binder that has a strong affinity for resins and organic paints. Using these products in combination, we can substantially increase the anti-stain functionality of coatings even in conditions which of high concentrations of exhaust gases and which would typically result in substantial stains. These coatings can also easily be rinsed clean.

The Need for a Stain-Prevention Coating that Took Advantage of our Binder Technology

 

Challenge

Resolution

Photocatalyst Coating for Areas Exposed to Light

(1)Because the outer coating of most road signs and equipment tends to be resins or organic membranes, the NOX, SOX and particularly PM (particulate matter or black smoke) from vehicular exhaust contributes to the staining of the surface because of static electricity.[NEED TO REDUCE STATIC ELECTRICITY]

Using ATO provided by Mitsubishi Materials, static electricity is substantially reduced (with a surface resistivity of 107~8?). Stains have difficulty attaching and are easily washed away.

(2) Because resins and organic membranes are broken down by photocatalysts, the resins and/or membrane would soon be destroyed without a strongly adhesive inorganic primer.[NEED FOR SPECIALIZED PRIMER FOR RESINS]

Completion of an inorganic binder that can be used with resins and films. Quick-drying. Surprising adhesion to photocatalyst top coat.

(3) Because the speed with which signage is soiled is fast on high traffic roads, a coating can not be used unless it is a strong photocatalyst and can be obtained relatively inexpensively.[NEED FOR INORGANIC BINDER WITH EXPOSED TITANIUM DIOXIDE ON THE SURFACE]

With a highly adherent silica binder, this coating firmly attaches to the substrate and incorporates a visible-light activated titanium dioxide photocatalyst with unsurpassed photocatalytic ability. With anti-static properties, this coating stays clean longer than competing titanium dioxide coatings, thus retaining its photocatalytic effect longer. Even in the absence of light, the superhydrophilic effect will enable easy cleaning. This is the most complete photocatalyst system on the market.

Anti-mold, Anti-stain Coating for Dark and/or Moldy Areas

(1) In dark or poorly lit areas such as tunnels, subways, underground shopping areas and the north faces of buildings, photocatalyst coatings have little effect. [NEED FOR ANTI-STATIC, INORGANIC BINDER]

Even where light does not reach, the way stains and dirt attach are completely different with an anti-static coating. Moreover, because of the silica binder, stains are easily removed in washing resulting in savings from reduced number of washings and reduced time per wash.

Mold grows in humid areas.[NEED FOR DURABLE COATING WITH LONG-LASTING ANTI-MOLD EFFECTS]

We have developed an adhesive silica coating that reduces static electricity and fights mold. Single-liquid that can be used for inorganic, organic and resins. Passed three year anti-mold activity test. Perfect for locations where mold grows easily.

Sketch’s Binder Technology

All surfaces, including glass, polycarbonates and stainless steel, may appear flat, but in fact they have minute bumps and indentations that cannot be seen. Using our binder technology, it is now possible to bind to virtually any material by making use of a variety of silicon particles between 5 and 30 nanometers in size. And because we are using very small particles of silicon, those particles that must be exposed to the surface to be effective such as the photocatalyst titanium dioxide or the static-electricity reducer tin oxide are easily able to reach the surface to achieve a high rate of functionality. Because each substrate is different, the manufacturer is happy to work with customers to select the best binder for a given substrate.

The Unique Characteristics of Sketch’s Binder

(1)   Highly adhesive coating that adheres whether organic or inorganic. Please note that the appropriate primer may vary with the substrate.

(2)   Extremely safe, reliable and long-lasting because it is inorganic.

(3)   Highly transparent because it uses minute silica particles (10~30nm).

(4)   By controlling the placement of the silica particles, we are able to ensure that adequate portions of the photocatalyst break through the surface and provide the photocatalytic effect. Please note that if a product’s binder is not effective, the binder itself may cover the photocatalyst and reduce the catalytic effect.

(5)   Appropriate for all markets, including professional use, DIY and OEM markets.

(6)   Effective with a membrane of only 0.1~0.2 microns thick, one liter can cover up to 100 square meters.

(7)   Because the membrane is strong, the cost is very low making it attractive to all markets.

(8)   A coat easy enough for anyone to apply. Formulated to go on evenly without blotches. Applies directly to the substrate as it is. A very uniform coat can be obtained by applying with a specialized spray gun.

Staining Mechanism – Characteristics of Airborne Pollutants

Thick oily stains easily stick to any surface which becomes even more soiled as dirt and dust particles attach to the spot. Light particles not containing oil float in the air and come into contact with nearly all surfaces and make oily stains even worse when they combine with them. These particles are initially attracted to external walls, tiles and glass by static electricity.
Exhaust fumes from automobiles (NOX, SOX, etc.), smoke from construction sites and restaurants and pollen dust, dirt, sand, particulate matter
The key to protecting againststains is to reduce static electricity
Visible Light Photocatalyst means that either sunlight or fluorescent light will break down the organic matter in the oil and because of the superhydrophilic function, water will loosen the stain and wash it away. Dust, dirt, sand, particulate matter and other minute pollutants floating in the air are unable to attach to surfaces coated with ATO because the surface is highly conductive.
Photocatalysts’ dual function of decomposing organic matter and generating superhydrophilic self-cleaning coating + Reducing Static Electricity (ATO) + Mold Reduction Function

Stain Prevention, Mold Resistance, Deodorizing, Anti-Bacterial – Aftermarket Channels

ALL MARKETS:
External building trim Cars,buses, trucks, trains Billboards
Home external remodeling Boats Road signs, guardrails
Bathrooms Airplanes Furniture
Kitchens Retail stores Lights

ALL SUBSTRATES:
Glass Mirrors Aluminum Stainless Steel
Stone Polycarbonates Acrylics Film
Steel plates Membranes External materials Internal Materials

(1) Making it difficult for stains to attach Reduce static electricity – KEY POINT
(2) Decompose stains that do attach Visible Light Photocatalyst
(3) Wash away stains that do attach with rain or light rinse Easy maintenance
(4) Long-lasting anti-mold function Maintain beauty of surface

Comparison with Other Companies’ Products

 

Photocatalyst Coating

Non-Light, Stain Prevention Coating

Feature

Toto Hydrotech

Matsushita Denko Furessera

Sketch

GlassBell AVT

INAX

MicroGuard

Sketch

GlassBell AM

Ingredients

SiO2

TiO2

SiO2

Visible-light activated TiO2

ATO

Ag+

SiO2

Antibacterial solution

SiO2

ATO

Anti-mold solution

Ag+

Superhydrophilicity

UV required

Effective immediately;

3Effective without light (5%)

Light not required

Effective immediately;

Effective without light (5%)

Anti-Static Electricity

3Little effect; NOX, SOX and dirt attach easily

Because of the anti-static effect of ATO, dirt does not attach easily and is removed without difficulty; 107~8?

Little effect; NOX, SOX and dirt attach easily

3Because of the anti-static effect of ATO, dirt does not attach easily and is removed without difficulty; 107~8?

Photocatalyitc Stain Prevention

Little effect

Effective (visible light)

No effect

No effect

Anti-mold efficacy

Cannot mix in anti-mold solution

Cannot mix in anti-mold solution

Anti-bacterial solution – uncertain effect on mold

Anti-mold solution

 

 

 

 

 

 

 

Photocatalyst Coating

Non-Light, Stain Prevention Coating

Feature

Toto Hydrotech

Matsushita Denko Furessera

Sketch

GlassBell AVT

INAX

MicroGuard

Sketch

GlassBell AM

Number of coats

1 primer + 2 top coats

1 primer + 2 top coats

1 top coat

1 top coat

Maintenance?

Necessary

Necessary

Unnecessary

Unnecessary

Strength of adhesion to resins, paints and billboards

Inorganic primer necessary

We have a fast-drying inorganic primer designed for resins and paints

Adheres

Strong adhesion without a primer

3Transparency and degree of work at time of application

Difficult

Transparent

Transparent

Transparent, simple, fast

Application cost

Expensive $40-50/m^2

Expensive $30+/m^2

Expensive $30+/m^2

Inexpensive $10-20/m^2

Area per liter applied

30m^2

50m^2

30m^2

50m^2

Overall evaluation

Main photocatalytic product – the primary issues are application and the need for an organic primer

Ease of application improved by fast-drying primer designed for resins and paints; stronger anti-static electric effect thatn other photocatalytic products; perfect for road-related signs and materials

Please note that this is not a photocatalyst, but is an anti-stain coating

By incorporating an anti-mold solution that can be applied in humid locations not reached by light (tunnels, subways, underground shopping areas; north faces of buildings), the anti-stain feature is enhanced; maintenance is simple and inexpensive.

Stain-Prevention Coating for Road Facilities and Related Materials

Site of Application

Substrate

Source of Stain

Liquid Coating

Volume of Coating per Area

Tunnels

Subways

Underground Shopping areas

Cement

Tile

NOX, SOX, PM

Dust, pollen

Oily stains

Mold

Anti-static electric and anti-mold coating

[GlassBell AM]

50m^2/L

Guardrails

Poles

Road materials

Train cars

Organic paint coating

NOX, SOX, PM

Dust, pollen

Oily stains

Mold

Inorganic silica primer

[AVT-PM]

Anti-static electric and photocatalyst coating

[GlassBell AVT]

50~100m^2/L

Sound walls

Billboards

Traffic signs

Traffic signals

Safety materials

Resins

NOX, SOX, PM

Dust, pollen

Oily stains

Acid Rain

Same

50~100m^2/L

Tollbooths

Buildings

Organic paint coating

Glass

NOX, SOX, PM

Dust, pollen

Oily stains

Mold (northface)

 

Same except that on north faces of buildings, apply [GlassBell AM]

50~100m^2/L

Product Features

GLASSBELL AM

  1. Developed Stain-prevention coating with anti-static electric features and anti-mold ability by taking an inorganic silica binder, adding Mitsubishi Materials ATO to control static electricity (107~8?) and silver ions to prevent mold.
  2. Perfect for dark, humid locations (tunnels, subways, underground shopping areas and north faces of buildings).
  3. Exhaust gases and airborne dust and dirt have more difficulty attaching due to the anti-static electricity effect and because of the hydrophilicity resulting from the inorganic silica coating that dust and dirt which does happen to attach is more easily removed.
  4. The anti-mold effect from both the iodine and the silver ions is long-lasting.
  5. Application without a primer is a simple, single coating.

GLASSBELL AVT

  1. Developed photocatalyst coating with anti-static electric features by taking an inorganic silica binder, adding Mitsubishi Materials ATO to control static electricity (107~8?) and visible-light activated titanium dioxide.
  2. Used in combination with the primer (below) that was developed for photocatalysts, resins commonly used in connection with roadways (sound-reduction barriers, billboards, traffic signals, safety materials) and organic membranes (guardrails, poles, buildings, etc.) are made resistant to stains by reducing static electricity and are cleaned by the photocatalytic action of the stongly active visible-light activated titanium dioxide that breaks down organic matter that does attach to the surface. 
  3. Given the synergistic interaction of the easy-to-clean in the rain coating and the anti-static electricity effect, the stain prevention ability of this product opens up a substantial lead over competing photocatalysts.

AVT-PM

    1. This is the inorganic primer for the GlassBell AVT coat described above.
    2. This is a primer developed for resins that has superior adhesive ability for both resins and organic paints that are commonly used on or near roadways.
    3. Because this primer is fast drying, GlassBell AVT can be applied efficiently.

Stain-Prevention Coating for Road Facilities and Related Materials

Product Name

Ingredients

Application Area

GlassBell AM

Anti-static electric and anti-mold coating

SiO2 (silica hardcoat)

Methanol (dispersion)

ATO (anti-static electric 107~8?)

M (anti-mold solution)

Ag+ (silver ions)

50 m^2 per liter

GlassBell AVT

Anti-static electric and photocatalyst coating

SiO2 (silica hardcoat)

Methanol (dispersion)

ATO (anti-static electric 107~8?)

VT (visible-light activated titanium dioxide)

Ag+ (silver ions)

50 m^2 per liter

AVT-PM

Inorganic adhesive primer for use with photocatalyst coating GlassBell AVT

SiO2 (adhesive binder)

Methanol (dispersion)

ATO (trace amounts – adhesive binder)

50 m^2 per liter

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