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Need for Stain Protection -
Sketch -
Unique Characteristics -
Stain Mechanism -
Stain Prevention -
Products Comparison -
Road Facilities -
Product Features
ASGARDPRO™
Specialized anti-static coating
For tunnels, subways, guardrails and other ROADway facilities
Delphi Labs is preparing to introduce to the US market a proven and innovative protective coating that will turn the tile surfaces of tunnels into easy-maintenance surfaces. The ultra-thin silica coating includes zinc oxide to reduce static electricity and iodine to resist mold. This product is already being purchased by the Japan Highway Association for similar applications. We expect this product to be available for use in the United States by the summer of 2006.
This product is formulated and manufactured by Sketch Co., Ltd, a pioneer in binder technology.
The Development of the Product
Today, in the stain prevention market, photocatalytic self-cleaning coatings using titanium dioxide are rapidly expanding the market throughout the world. However, because photocatalysts have the ability to break down organic matter, primers are absolutely required when applying to surfaces that are common in highway-related signage, safety equipment and building materials such as paint, polycarbonates, acrylics, FRP (fiberglass reinforced plastics) and resins. Unfortunately, there are no inorganic primers available today that adhere strongly to these resins. Moreover, because polycarbonates and acrylics have complex molecular structures, when the surface becomes water-repellant, the surface attracts dirt and grime (because of static electricity) and becomes easily tarnished or stained. There is thus a strong need for an inorganic primer or a top coat with dual capabilities of photocatalysis and reducing static electricity and still bind strongly to these resin surfaces
Furthermore, there is a need for a stain prevention coating that can substitute for photocatalytic coatings in locations that do not receive much light such as tunnels, subways, underground shopping areas and the north faces of buildings and that can be easily cleaned by periodic rinsing with water. And, especially in humid areas which give rise to mold problems, there is a need for a coating with an anti-mold function.
After many years of research, based upon our company’s binder technology, we have successfully developed a binder and a primer for resins that resolves the issues identified above. To our inorganic binder, we have added ATO (antimony doped tin oxide from Mitsubishi Materials) which has superb anti-static electric functions. To this strong base, we have added a powerful visible-light photocatalyst composed of titanium dioxide for those areas receiving light and an anti-mold formulation with iodine and silver ions for those areas not receiving adequate light.
We have also succeeded in preparing a firm inorganic binder that has a strong affinity for resins and organic paints. Using these products in combination, we can substantially increase the anti-stain functionality of coatings even in conditions which of high concentrations of exhaust gases and which would typically result in substantial stains. These coatings can also easily be rinsed clean.
The Need for a Stain-Prevention Coating that Took Advantage of our Binder Technology
|
Challenge |
Resolution |
Photocatalyst Coating for Areas Exposed to Light |
(1)Because the outer coating of most road signs and equipment tends to be resins or organic membranes, the NOX, SOX and particularly PM (particulate matter or black smoke) from vehicular exhaust contributes to the staining of the surface because of static electricity.[NEED TO REDUCE STATIC ELECTRICITY] |
Using ATO provided by Mitsubishi Materials, static electricity is substantially reduced (with a surface resistivity of 107~8?). Stains have difficulty attaching and are easily washed away. |
(2) Because resins and organic membranes are broken down by photocatalysts, the resins and/or membrane would soon be destroyed without a strongly adhesive inorganic primer.[NEED FOR SPECIALIZED PRIMER FOR RESINS] |
Completion of an inorganic binder that can be used with resins and films. Quick-drying. Surprising adhesion to photocatalyst top coat. |
(3) Because the speed with which signage is soiled is fast on high traffic roads, a coating can not be used unless it is a strong photocatalyst and can be obtained relatively inexpensively.[NEED FOR INORGANIC BINDER WITH EXPOSED TITANIUM DIOXIDE ON THE SURFACE] |
With a highly adherent silica binder, this coating firmly attaches to the substrate and incorporates a visible-light activated titanium dioxide photocatalyst with unsurpassed photocatalytic ability. With anti-static properties, this coating stays clean longer than competing titanium dioxide coatings, thus retaining its photocatalytic effect longer. Even in the absence of light, the superhydrophilic effect will enable easy cleaning. This is the most complete photocatalyst system on the market. |
Anti-mold, Anti-stain Coating for Dark and/or Moldy Areas |
(1) In dark or poorly lit areas such as tunnels, subways, underground shopping areas and the north faces of buildings, photocatalyst coatings have little effect. [NEED FOR ANTI-STATIC, INORGANIC BINDER] |
Even where light does not reach, the way stains and dirt attach are completely different with an anti-static coating. Moreover, because of the silica binder, stains are easily removed in washing resulting in savings from reduced number of washings and reduced time per wash. |
Mold grows in humid areas.[NEED FOR DURABLE COATING WITH LONG-LASTING ANTI-MOLD EFFECTS] |
We have developed an adhesive silica coating that reduces static electricity and fights mold. Single-liquid that can be used for inorganic, organic and resins. Passed three year anti-mold activity test. Perfect for locations where mold grows easily. |
Sketch’s Binder Technology
All surfaces, including glass, polycarbonates and stainless steel, may appear flat, but in fact they have minute bumps and indentations that cannot be seen. Using our binder technology, it is now possible to bind to virtually any material by making use of a variety of silicon particles between 5 and 30 nanometers in size. And because we are using very small particles of silicon, those particles that must be exposed to the surface to be effective such as the photocatalyst titanium dioxide or the static-electricity reducer tin oxide are easily able to reach the surface to achieve a high rate of functionality. Because each substrate is different, the manufacturer is happy to work with customers to select the best binder for a given substrate.
The Unique Characteristics of Sketch’s Binder
(1) Highly adhesive coating that adheres whether organic or inorganic. Please note that the appropriate primer may vary with the substrate.
(2) Extremely safe, reliable and long-lasting because it is inorganic.
(3) Highly transparent because it uses minute silica particles (10~30nm).
(4) By controlling the placement of the silica particles, we are able to ensure that adequate portions of the photocatalyst break through the surface and provide the photocatalytic effect. Please note that if a product’s binder is not effective, the binder itself may cover the photocatalyst and reduce the catalytic effect.
(5) Appropriate for all markets, including professional use, DIY and OEM markets.
(6) Effective with a membrane of only 0.1~0.2 microns thick, one liter can cover up to 100 square meters.
(7) Because the membrane is strong, the cost is very low making it attractive to all markets.
(8) A coat easy enough for anyone to apply. Formulated to go on evenly without blotches. Applies directly to the substrate as it is. A very uniform coat can be obtained by applying with a specialized spray gun.
Staining Mechanism – Characteristics of Airborne Pollutants
| Thick oily stains easily stick to any surface which becomes even more soiled as dirt and dust particles attach to the spot. |
Light particles not containing oil float in the air and come into contact with nearly all surfaces and make oily stains even worse when they combine with them. These particles are initially attracted to external walls, tiles and glass by static electricity. |
| Exhaust fumes from automobiles (NOX, SOX, etc.), smoke from construction sites and restaurants and pollen |
dust, dirt, sand, particulate matter |
| The key to |
 |
protecting againststains is to reduce |
 |
static electricity |
| Visible Light Photocatalyst means that either sunlight or fluorescent light will break down the organic matter in the oil and because of the superhydrophilic function, water will loosen the stain and wash it away. |
Dust, dirt, sand, particulate matter and other minute pollutants floating in the air are unable to attach to surfaces coated with ATO because the surface is highly conductive. |
| Photocatalysts’ dual function of decomposing organic matter and generating superhydrophilic self-cleaning coating + Reducing Static Electricity (ATO) + Mold Reduction Function |
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Stain Prevention, Mold Resistance, Deodorizing, Anti-Bacterial – Aftermarket Channels
| ALL MARKETS: |
| External building trim |
Cars,buses, trucks, trains |
Billboards |
| Home external remodeling |
Boats |
Road signs, guardrails |
| Bathrooms |
Airplanes |
Furniture |
| Kitchens |
Retail stores |
Lights |
| ALL SUBSTRATES: |
| Glass |
Mirrors |
Aluminum |
Stainless Steel |
| Stone |
Polycarbonates |
Acrylics |
Film |
| Steel plates |
Membranes |
External materials |
Internal Materials |
| (1) Making it difficult for stains to attach |
Reduce static electricity – KEY POINT |
| (2) Decompose stains that do attach |
Visible Light Photocatalyst |
| (3) Wash away stains that do attach with rain or light rinse |
Easy maintenance |
| (4) Long-lasting anti-mold function |
Maintain beauty of surface |
Comparison with Other Companies’ Products
|
Photocatalyst Coating |
Non-Light, Stain Prevention Coating |
Feature |
Toto Hydrotech
Matsushita Denko Furessera
|
Sketch
GlassBell AVT
|
INAX
MicroGuard
|
Sketch
GlassBell AM
|
Ingredients |
SiO2
TiO2
|
SiO2
Visible-light activated TiO2
ATO
Ag+
|
SiO2
Antibacterial solution
|
SiO2
ATO
Anti-mold solution
Ag+
|
Superhydrophilicity |
UV required |
Effective immediately;
3Effective without light (5%)
|
Light not required |
Effective immediately;
Effective without light (5%)
|
Anti-Static Electricity |
3Little effect; NOX, SOX and dirt attach easily |
Because of the anti-static effect of ATO, dirt does not attach easily and is removed without difficulty; 107~8? |
Little effect; NOX, SOX and dirt attach easily |
3Because of the anti-static effect of ATO, dirt does not attach easily and is removed without difficulty; 107~8? |
Photocatalyitc Stain Prevention |
Little effect |
Effective (visible light) |
No effect |
No effect |
Anti-mold efficacy |
Cannot mix in anti-mold solution |
Cannot mix in anti-mold solution |
Anti-bacterial solution – uncertain effect on mold |
Anti-mold solution |
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Photocatalyst Coating |
Non-Light, Stain Prevention Coating |
Feature |
Toto Hydrotech
Matsushita Denko Furessera
|
Sketch
GlassBell AVT
|
INAX
MicroGuard
|
Sketch
GlassBell AM
|
| Number of coats |
1 primer + 2 top coats |
1 primer + 2 top coats |
1 top coat |
1 top coat |
Maintenance? |
Necessary |
Necessary |
Unnecessary |
Unnecessary |
Strength of adhesion to resins, paints and billboards |
Inorganic primer necessary |
We have a fast-drying inorganic primer designed for resins and paints |
Adheres |
Strong adhesion without a primer |
| 3Transparency and degree of work at time of application |
Difficult |
Transparent |
Transparent |
Transparent, simple, fast |
Application cost |
Expensive $40-50/m^2 |
Expensive $30+/m^2 |
Expensive $30+/m^2 |
Inexpensive $10-20/m^2 |
Area per liter applied |
30m^2 |
50m^2 |
30m^2 |
50m^2 |
Overall evaluation |
Main photocatalytic product – the primary issues are application and the need for an organic primer |
Ease of application improved by fast-drying primer designed for resins and paints; stronger anti-static electric effect thatn other photocatalytic products; perfect for road-related signs and materials |
Please note that this is not a photocatalyst, but is an anti-stain coating |
By incorporating an anti-mold solution that can be applied in humid locations not reached by light (tunnels, subways, underground shopping areas; north faces of buildings), the anti-stain feature is enhanced; maintenance is simple and inexpensive. |
Stain-Prevention Coating for Road Facilities and Related Materials
Site of Application |
Substrate |
Source of Stain |
Liquid Coating |
Volume of Coating per Area |
|
Tunnels
Subways
Underground Shopping areas
|
Cement
Tile
|
NOX, SOX, PM
Dust, pollen
Oily stains
Mold
|
Anti-static electric and anti-mold coating
[GlassBell AM]
|
50m^2/L
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Guardrails
Poles
Road materials
Train cars
|
Organic paint coating |
NOX, SOX, PM
Dust, pollen
Oily stains
Mold
|
Inorganic silica primer
[AVT-PM]
Anti-static electric and photocatalyst coating
[GlassBell AVT]
|
50~100m^2/L
|
|
Sound walls
Billboards
Traffic signs
Traffic signals
Safety materials
|
Resins |
NOX, SOX, PM
Dust, pollen
Oily stains
Acid Rain
|
Same |
50~100m^2/L |
|
Tollbooths
Buildings
|
Organic paint coating
Glass
|
NOX, SOX, PM
Dust, pollen
Oily stains
Mold (northface)
|
Same except that on north faces of buildings, apply [GlassBell AM] |
50~100m^2/L |
Product Features
GLASSBELL AM
- Developed Stain-prevention coating with anti-static electric features and anti-mold ability by taking an inorganic silica binder, adding Mitsubishi Materials ATO to control static electricity (107~8?) and silver ions to prevent mold.
- Perfect for dark, humid locations (tunnels, subways, underground shopping areas and north faces of buildings).
- Exhaust gases and airborne dust and dirt have more difficulty attaching due to the anti-static electricity effect and because of the hydrophilicity resulting from the inorganic silica coating that dust and dirt which does happen to attach is more easily removed.
- The anti-mold effect from both the iodine and the silver ions is long-lasting.
- Application without a primer is a simple, single coating.
GLASSBELL AVT
- Developed photocatalyst coating with anti-static electric features by taking an inorganic silica binder, adding Mitsubishi Materials ATO to control static electricity (107~8?) and visible-light activated titanium dioxide.
- Used in combination with the primer (below) that was developed for photocatalysts, resins commonly used in connection with roadways (sound-reduction barriers, billboards, traffic signals, safety materials) and organic membranes (guardrails, poles, buildings, etc.) are made resistant to stains by reducing static electricity and are cleaned by the photocatalytic action of the stongly active visible-light activated titanium dioxide that breaks down organic matter that does attach to the surface.
- Given the synergistic interaction of the easy-to-clean in the rain coating and the anti-static electricity effect, the stain prevention ability of this product opens up a substantial lead over competing photocatalysts.
AVT-PM
- This is the inorganic primer for the GlassBell AVT coat described above.
- This is a primer developed for resins that has superior adhesive ability for both resins and organic paints that are commonly used on or near roadways.
- Because this primer is fast drying, GlassBell AVT can be applied efficiently.
Stain-Prevention Coating for Road Facilities and Related Materials
Product Name |
Ingredients |
Application Area |
|
GlassBell AM
Anti-static electric and anti-mold coating
|
SiO2 (silica hardcoat)
Methanol (dispersion)
ATO (anti-static electric 107~8?)
M (anti-mold solution)
Ag+ (silver ions)
|
50 m^2 per liter |
|
GlassBell AVT
Anti-static electric and photocatalyst coating
|
SiO2 (silica hardcoat)
Methanol (dispersion)
ATO (anti-static electric 107~8?)
VT (visible-light activated titanium dioxide)
Ag+ (silver ions)
|
50 m^2 per liter |
|
AVT-PM
Inorganic adhesive primer for use with photocatalyst coating GlassBell AVT
|
SiO2 (adhesive binder)
Methanol (dispersion)
ATO (trace amounts – adhesive binder)
|
50 m^2 per liter |
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